Marie-Adélaïde of Luxembourg isn't a name you might have heard. This woman did a ton of stuff though — including pretty much running away from her own country.
Marie-Adélaïde, Grand Duchess of Luxembourg

Marie-Adélaïde of Luxembourg isn't a name you might have heard. This woman did a ton of stuff though — including pretty much running away from her own country.
Margherita of Savoy was the first woman to hold the title of Queen of Italy. She's also my favorite historical figure because she's just amazing.
Caroline of Brunswick was a Queen of England who hated her husband and loved Italy (and also maybe her servant). Here’s the story of the injured queen of England.
Juliane of Saxe-Coburg-Saalfeld was the Grand Duchess who ran away from Russia on multiple occasions. Here's her very full story.